Pyrite Mineral Oxidation

Pyrite Oxidation Kinetics - How Fast does Pyrite Oxidize

Pyrite oxidation has been studied extensively, in the past, because of its importance in sulfide mineral separations by flotation, in the generation of acid in mine waters and in leaching of pyrite

Pyrite Oxidation Mechanism by Oxygen in Aqueous Medium

Pyrite oxidation is related to many environmental and technological issues, and its mechanism has not been completely understood A stone picture of the pyrite oxidation process in the presence of oxygen and water was proposed in the present investigation

Pyrite Mineral | Uses and Properties - Geology

Pyrite is a brass-yellow mineral with a bright metallic luster It has a stone composition of iron disulfide (FeS2) and is the most common sulfide mineral It forms at high and low temperatures and occurs, usually in small quantities, in igneous, metamorphic, and sedimentary rocks worldwide


The most common, iron-bearing sulphides – pyrite, pyrrhotite – usually became part of the mining waste and are stored in mine waste facilities where these minerals are exposed to atmospheric water and oxygen that results in quick oxidation processes

How do pyrite and pyrrhotite damage building foundations

Pyrite and pyrrhotite are minerals known as iron sulfides When iron sulfides are exposed to water and oxygen, a series of stone reactions breaks down the iron sulfides and forms new minerals called sulfates These sulfates take up more space than the original iron sulfides

Pyrite oxidation: a state-of-the-art assessment of the

The oxidation of pyrite to release ferrous iron and sulfate ions to solution involves the transfer of seven electrons from each sulfur atom in the mineral to an aqueous oxidant Because only one or, at most, two electrons can be transferred at a time, the overall oxidation process is quite complex


The pyrite oxidation rates, normalized for exposed surface area, ranged from 4 × 10 −10 to 18 × 10 −10 mol m −2 s −1 and tended to increase as drainage pH decreased from 73 to 33

Pyrite: The mineral pyrite information and pictures

The Mineral pyrite Pyrite is sometimes called Fools Gold because of its similarity in Pyrite is usually in spherical concretions that contain internal shrinkage fractures, and the iridescence is caused by oxidation POLYMORPHS: Marcasite: USES: Pyrite was once used as a source of sulfur,

Pyrite Oxidation: Review and Prevention Practices

Pyrite oxidation is also known as pyrite ‘disease’, pyrite ‘rot’, and pyrite ‘decay’, and it is caused and Pyrite (FeS 2 ) is a common mineral found in sedimentary rock and fossils, and its decay is a major problem in the conservation of fossil specimens Pyrite oxidation, also referred to as pyrite disease or pyrite decay, is

The mechanisms of pyrite oxidation and leaching: A

Pyrite oxidation is economically important in mineral flotation and leaching, two industrial methodologies used to separate pyrite from other minerals of value Oxidation can impart hydrophobicity or hydrophilicity to pyrite surfaces and hence influences interactions with collectors during flotation [5]

Pyrite Oxidation: Review and Prevention Practices

What is Pyrite Oxidation? Pyrite (FeS 2 ) is one of the most widespread and persistent minerals and occurs in sedimentary, metamorphic, and igneous rocks Pyrite grows in crystalline forms, typically cubic, octahedral, or more rarely pyritohedral (irregular dodecahedral with twelve identical pentagonal faces) The crystal can be several

Pyrite: The mineral pyrite information and pictures

The Mineral pyrite Enormous deposits of Pyrite in the form of small crystal clusters exist in the Huaron Mining District in Peru Other outstanding Peruvian localities are the Quiruvilca Mine, La Libertad; and the Huanzala, Huánuco Most of the amateur collector Pyrite comes from the …

About kinetic pyrite oxidation - The Geochemist's

Dec 05, 2014 · In comparison with Pyrite_oxidation_1 and Pyrite_oxidation_2, the only difference is whether the volume of pyrite is set in Initial pane or Reactants pane, simply As you said, I tried to establish a fluid chemistry using SpecE8 Unfortunately, I couldn’t

Pyrite - an overview | ScienceDirect Topics

The oxidation of pyrite can occur when the mineral surface is exposed to an oxidant and water, either in oxygenated or anoxic systems, depending on the oxidant The process is complex and can involve chemical, biological, and electrochemical reactions


PYRITE OXIDATION RATES FROM HUMIDITY CELL TESTING OF GREENSTONE ROCK1 Kim A Lapakko2 David A Antonson2 the rate of sulfide mineral oxidation increases as pH decreases into a Pyrite oxidation rates were calculated based on the pyrite surface area that would be exposed

Supergene Oxidation of Copper Deposits - pyriteutahedu

Pyrite is a relatively refractory mineral in the replacement sequence; marcasite oxidizes more quickly than pyrite (Mason and Berry, 1968), and pyrrhotite oxidation is as …

pyrite cleaning « McDougall Minerals

Pyrite Crystals from the Victoria Mine, Navajún, La Rioja, Spain – 72 x 71cm In June, 2013, I was fortunate to be invited to visit Navajún, to see what is truly one of the most remarkable mineral occurrences known

Pyrite | mineral | Britannica

Pyrite, also called iron pyrite or fool’s gold, a naturally occurring iron disulfide mineral The name comes from the Greek word pyr, “fire,” because pyrite emits sparks when struck by steel

Oxidation of sulfide minerals, 4 Pyrite, chalcopyrite and

Oxidation of sulfide minerals, 4 Pyrite, chalcopyrite and pyrrhotite Article in stone Geology 23(1-4):225-237 · December 1978 with 232 Reads

Experimental determination of pyrite and molybdenite

centrations or the products of pyrite oxidation in the sub-micromolar range Due to these limitations, extrapolation of pyrite oxida-tion kinetics from different rate laws results in significant disagreement regarding pyrite oxidation rates at Archean pO 2 (Nicholson et al, 1988; Williamson and Rimstidt, 1994; Bolton et al, 2006)

52 stone Weathering – Physical Geology - opentextbcca

52 stone Weathering Oxidation is another very important stone weathering process The oxidation of the iron in a ferromagnesian silicate starts with the dissolution of the iron For olivine, the process looks like this, where olivine in the presence of carbonic acid is …

Pyrite - McGill School Of Computer Science

Euhedral cubic pyrite crystals The mineral pyrite, or iron pyrite, is iron sulfide, FeS2 It has isometric crystals that usually appear as cubes The cube faces may be striated (parallel lines on crystal surface or cleavage face) as a result of alternation of the cube and pyritohedron faces

Surface Oxidation of Pyrite as a Function of pH

Surface Oxidation of Pyrite as a Function of pH Minerals Engineering 2013 46-47, 45-51 Oxygen and sulfur isotope investigations of the oxidation of sulfide mixtures containing pyrite, galena, and sphalerite Claudia Heidel, Marion Tichomirowa, Manuela Junghans stone Geology 2013 342, 29-43

Minerals | Free Full-Text | Directional Oxidation of

The oxidation products of pyrite were examined by Raman spectroscopy and X-ray photoelectron spectroscopy Results showed that the aqueous oxidation of pyrite produced Fe(OH)3, Fe2O3, Fe2(SO4)3, and S8 on the surface

Pyrite Oxidation: Where Are We Now? – Geological Curators

Jul 10, 2018 · Pyrite Oxidation: Where Are We Now? Posted on July 10, 2018 September 13, 2018 by geocurators Written by Deborah Hutchinson , Geology Curator at Bristol Museum & Art Gallery

Mechanism of Bacterial Pyrite Oxidation - jbasmorg

tion of a number of different pyrite samples by "resting cells" ofF ferrooxidans Oneexception was a CaCO2-containing pyrite which resisted oxidation Upon pretreatment with HCl, which removed acid-soluble iron species as well as carbonates, this pyrite became susceptible to bacterial attack However, oxygen uptake was nonlinear andwaspreceded bya 2-hr lag period

Surface Oxidation of Pyrite as a Function of pH

Abstract Pyrite, the most abundant metal sulfide at the surface of Earth, plays a key role in many processes such as acid mine drainage, redox cycling of metals at oxic-anoxic boundaries of lake bottom, and degradation of pollutants The oxidation of pyrite was studied in batch experiments over a large range of pH (25−12), with trace oxygen

Pyrite oxidation mechanism in aqueous medium | Request PDF

The mineral pyrite is considered the most common form of the sulfide minerals Its oxidation is a very important process in nature, which involves in the redox recycling of iron

Pyrite: Mineral information, data and localities

About Pyrite Hide Pyrite is a very common mineral, found in a wide variety of geological formations from sedimentary deposits to hydrothermal veins and as a constituent of metamorphic rocks The brassy-yellow metallic colour of pyrite has in many cases lead to people mistaking it for Gold, hence the common nickname 'Fool's gold'

Pyrite Depression By Reduction Of Solution Oxidation Potential

Oxidation Potential Measurements Solution oxidation potential measurements of each pyrite flotation system were attempted; however, in oxyanion reductant systems, it …

Microbial Oxidation of Fe2+ and Pyrite Exposed to Flux of

Jun 13, 2013 · When pyrite cubes were intermittently exposed to fluxes of micromolar H 2 O 2, the reduced Fe 2+-Fe 3+ conversion rate in the solution (due to reduced microbial activity) weakened the Fe 3+-catalyzed oxidation of cubic pyrite and added to relative importance of H 2 O 2-driven oxidation in the corrosion of mineral surfaces for the treatments

Experimental Study of Pyrite Oxidation at pH 6-9 and 30°C

Experimental Study of Pyrite Oxidation at pH 6-9 and 30°C by Martin B Goldhaber Abstract catalyzed oxidation of iron-disulfide minerals producing sulfate ions that are carried with uranium-bearing ground water into reduced (iron sulfide and (or) organic carbon-bearing) rock

amrclearinghouseorg :::AMD Basics - PYRITE REACTIONS:::

The mineral pyrite (FeS2) and other sulfur containing minerals are common Also common is the occurrence of these minerals in the geologic strata in the vicinity of coal seams Mining coal inevitably involves exposing these pyritic materials to oxygen and water

Mineralogical and geochemical studies on pyrite and

Galena and chlcopyrite are commonly associated with acid-generating minerals, such as pyrite and pyrrhotite Ferric sulphate acid solutions, generated by the oxidation of iron sulphides can enhance the oxidation of lead and copper-bearing sulphide minerals (Jennings et al 2000; Nowak and Laajalehto 2000; Shapter et al

Thermal Gravimetric Analysis of Pyrite Oxidation at Low

THERMAL GRAVIMETRIC ANALYSIS OF PYRITE OXIDATION AT LOW TEMPERATURE By J E Pahlm an1 and G W Reim ers2 ABSTRACT Spontaneous oxidation and combustion of sulfides and resultant fires are serious problems in underground mines

Mechanism of Pyrite Dissolution in the Presence of

Feb 10, 1999 · The oxidation of pyrite (FeS2) in the presence of Thiobacillus ferrooxidans is a significant factor in the formation of acid mine drainage, an environmental problem of considerable concern (7) However, T ferrooxidans is used in commercial processes to extract gold from pyrite and arsenopyrite

Sedimentary Pyrite: A Window into the Microbial Past

Sedimentary Pyrite: A Window into the Microbial Past with detrital iron minerals produces pyrite (FeS2), a ubiquitous constituent of most marine This pyrite forms very early and close to the sediment surface, when the pore spaces of the sediment are teeming with microbes (Canfield and

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